Web你画的对甲基苯基磺酸根俗称 tosyl group, TsO- 。你提的问题是甲基磺酸根mesyl group, MsO- .所以有点对不上号。我找不到你说的磺酸根在哪儿,,,。 你的图里,需要对比的是TsO- 和 C2H5O- 的离去能力强弱。很明显是TsO- 更好 WebPROTECTING GROUPS 58 Methoxyethoxymethyl ethers (MEM) R-OH → R-OCH2OCH2CH2OMe stable to base and mild acid Formation: - MeOCH2CH2OCH2Cl, NaH, THF - MeOCH2CH2OCH2Cl, CH2Cl2, iPr2EtNTL 1976, 809 Cleavage - Lewis acids such as ZnBr2, TiCl4, Me2BBr2 C5H11O MEM-O O-Si(Ph)2tBu B S S Cl C5H11O HO O …
Synthetic Studies toward Dimeric Indole Alkaloids Based ... - 日 …
WebSulfonyl chlorides can by hydrolyzed with water or with an alcohol in the absence of acid or base. Basic catalysis is also used, though of course the salt is the product obtained. … WebIk geef toestemming om promoties en exclusieve kortingen te ontvangen . Registreer. NL . Australie ; Denemarken ; Duitsland ; Frankrijk ; Italie title credit stranger things
Total Synthesis of (â )-Lepenine - Journal of the American Chemical
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